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920-345 BCM50/450 Rls. 5.0 Installation and(R) Initial Configuration

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920-345 exam Dumps Source : BCM50/450 Rls. 5.0 Installation and(R) Initial Configuration

Test Code : 920-345
Test cognomen : BCM50/450 Rls. 5.0 Installation and(R) Initial Configuration
Vendor cognomen : Nortel
: 110 existent Questions

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Nortel BCM50/450 Rls. 5.0 Installation

latest Nortel utility unencumber offers SMBs New stages of Simplicity and Unified Communications | killexams.com existent Questions and Pass4sure dumps

typical application stream offers finished, most economical, and Scalable retort throughout structures and into arm workplaces

TORONTO, ONTARIO--(Marketwire - Nov. three, 2009) - miniature and medium-sized groups (SMBs) can obtain productivity, cost-reductions and the investment coverage notable to success in cutting-edge company ambiance with new unified communications-based mostly (UC) utility from Nortel* (OTCBB:NRTLQ). The latest software unlock 5.0 for Nortel's award-profitable enterprise Communications supervisor (BCM) adds new UC capabilities, together with unified presence, and stronger simplicity with the introduction of a typical application gallop for BCM50 and BCM450.

The Nortel BCM450 and BCM50 are Linux-primarily based IP/TDM PBXs supplying software-wealthy, all-in-one options for converged voice and records communications. The BCM50 serves businesses with as much as 50 clients while the higher skill BCM450 is suitable for becoming medium to broad organizations and arm places of work with up to 300 clients. every supports a merge of IP and digital purchasers and can enable enterprises to retailer up to 70 % of their common funding by reusing current device.

As Part of the new BCM Rls 5.0 application, BCM450 and BCM50 supply SMBs with dynamic UC points fancy InTouch, which delivers suitable federated presence, and widely wide-spread integrated communications purposes and capabilities. InTouch lets clients talk with no pains with anybody of their own directory – throughout Microsoft Outlook, Nortel BCM, MSN, and Skype for click on-to-name, click on-to-IM, and click on-to-e mail. via connecting americans quicker, improving collaboration and speeding up the time to determination, Nortel estimates that unified communications can succor companies recognise charge-discount rates and an enlarge in productiveness of up to 18 %.

closing yr, the Nashville convention and guests Bureau** (NCVB) leveraged its BCM450 retort to ebook more than 650,000 lodge rooms while marketing tourism on behalf of quite a few partners. NCVB is now trialing BCM Rls 5.0 and plans to roll out the InTouch software within the coming weeks. Kay Hopwood, NCVB's director of counsel expertise, is anticipating seeing precise-time presence for everybody on the network and having a view into overlooked calls even when a caller doesn't leave a voicemail. For now, NCVB is enjoying the first BCM Rls 5.0 feature it deployed, FindMe/FollowMe (FMFM), which enables simultaneous ringing of up to five additional exterior contraptions. "every convoke is potential company," mentioned Hopwood. "With BCM's FindMe/FollowMe ability, their income crew under no circumstances has to omit a different earnings-producing convoke once again."

Minitel**, a premier Nortel associate featuring provider across Canada, moreover chose to crucible BCM Rls 5.0 in its personal workplace creation device. Its Toronto vice president of Operations, Dan Silverman, turned into so jubilant with the progress of the in-residence crucible he convinced a broad accounting enterprise customer to installation it as well. "The installation became as antiseptic as can breathe and the client is now rolling out both InTouch and FindMe/FollowMe to numerous clients of their corporation with no trouble. They had been in a position to collect their client up to quicken on the interface and rolling the application out with the aid of themselves in less than an hour," mentioned Silverman.

Mexico's Universidad Latinoamericana** (ULA) similarly verified the latest BCM application with positive results. "we're in the enterprise of teaching contemporaneous formative years and making ready them for the future and the challenges forward," spoke of Mario Ahumada Sandoval, subdirector of programs, ULA. "To execute so, they signify number on having the newest in communications expertise that helps us offer a prosperous UC journey for team of workers and college students. Trialling BCM Rls 5.0, they found that the product's new characteristic set enhances their UC event, while maximizing outfit already in region."

BCM50 consumer, Philkeram-Johnson**, the oldest ceramic tile producer in Greece, moreover welcomed the brand new application liberate. "Our Nortel BCM50 gives us scope to develop, when it comes to potential and performance, and it provides the elements they necessity to evolve to a unified communications ambiance," stated Christos Syropoulos, commercial manager, Philkeram-Johnson. "we are constantly in search of methods to boost their items and their productiveness in order to reply more straight away to valued clientele. i am desperate to find out more about the new facets attainable in BCM Rls 5.0 and how they can employ them to enhance their communications."

in addition to the InTouch and FMFM capabilities, BCM Rls 5.0 lets a person forward a voice message the employ of a file in order that it may moreover breathe performed or study by means of any cellular outfit on this planet. Meet-Me Conferencing for BCM now provides up to one hundred twenty five ports with uphold for as many as 300 users. skilled cognomen Recording, a skill customarily presented via a 3rd party is moreover attainable as a Part of the latest BCM free up.

As an extra capability of streamlining expenses and operations making it even more essential for SMBs and Nortel channel companions to installation, provision, and migrate pre-current facts, the brand new BCM50 and BCM450 portfolio comprises criterion software and purposes, O/S, working towards, accreditation, consumer interfaces, and documentation.

Dell'Oro ranks Nortel's SMB portfolio #1 on the earth in number of hybrid-IP lines shipped and #2 in SMB market earnings for the 2nd quarter 2009. Nortel's BCM options are localized and sold in over one hundred twenty nations via greater than a thousand channels.

Hear from greater BCM users and partners:

  • "FindMe/FollowMe and Message Forwarding permit constitution Telecom's** revenue and technical group of workers to breathe greater attainable to their shoppers, even if within the workplace or on the highway. With the skill for individual users to personalize these points to their liking via an internet-primarily based GUI device Mailbox supervisor. Their gadget administrator now not has to manufacture each day changes. FMFM and the skill to seamlessly switch calls between their desk phones and mobile phones has moreover allowed us to lower their charges, deliver their group of workers with greater flexibility, and boost their availability to consumers." – David Harper, voice techniques engineer, constitution Telecom - Canada
  • "Our office communications were primarily based solely on Nortel's BCM methods for years. They currently upgraded to the latest BCM know-how, preserving most of their prefatory funding in hardware and totality the funding in utility licenses. the brand new UC performance increases their productivity and saves time. It moreover allows us to connect to other programs fancy Communications Server 1000 and Microsoft OCS. With InTouch they are in a position to manipulate their online contacts at MSN and Skype from a separate software interface in MS Outlook, together with their workplace colleagues, shoppers, and companions." – Nikos Koulioumbis, SMB options director, UniNortel SA** - Greece
  • "inventive new facets corresponding to InTouch with federated presence, FindMe/FollowMe, professional cognomen Recording and superior CTI applications are totality extremely sterling productiveness enhancers so that it will redeem groups time and money and this basically resonated with the consumers they talked to at a recent seminar held in Nortel's Maidenhead workplace. They had enthusiastic feedback from attendees together with a London-primarily based voice and records options issuer who said he most loved the component of the seminar that concentrated on BCM Rls 5.0." – Thomas Jacques, managing director, 1st Communications** - UK
  • "The BCM product has always been one that they now accommodate been disdainful to present to their shoppers because of its converged voice and information solution for miniature and medium companies. As a longtime channel partner of Nortel's in Mexico, they gawk ahead to being able to present these very aspects, apart from newly better ones with the brand new utility free up of BCM Rls 5.0 with new points akin to FindMeFollowMe, expert convoke Recording, and more desirable CTI functions with a purpose to enlarge their consumer's productiveness." – Jorge Alberto Jimenez Hernandez, director of engineering, Innovaciones Telemáticas, S.A. de C.V.** (INTELEMATICA) - Mexico
  • About Nortel

    Nortel grants communications capabilities that manufacture the engage of enterprise Made primary a verisimilitude for their purchasers. Their next-generation technologies, for each provider company and traffic networks, succor multimedia and company-important applications. Nortel's applied sciences are designed to assist dispose of today's barriers to efficiency, pace and efficiency by using simplifying networks and connecting people to the information they want, when they want it. For more information, discuss with Nortel on the net at www.nortel.com. For the newest Nortel news, visit www.nortel.com/news.

    certain statements in this press unencumber might moreover comprise words equivalent to "could", "expects", "might also", "anticipates", "believes", "intends", "estimates", "aims", "envisions", "seeks" and different similar language and are regarded forward-looking statements or tips under relevant securities legislations. These statements are in keeping with Nortel's present expectations, estimates, forecasts and projections about the operating ambiance, economies and markets through which Nortel operates. These statements are territory to vital assumptions, risks and uncertainties, which can breathe tricky to prophesy and the precise outcome may well breathe materially distinctive from these contemplated in ahead-searching statements. For more information with cherish to certain of those and other elements, survey Nortel's Annual document on Form10-okay, Quarterly studies on benign 10-Q and different securities filings with the SEC. until otherwise required by pass of applicable securities laws, Nortel disclaims any aim or responsibility to update or revise any forward-looking statements, no matter if on account of new tips, future movements or in any other case.

    *Nortel, the Nortel logo and the Globemark are logos of Nortel Networks.

    **here is a 3rd party hyperlink as described in their internet linking practices.

    Use of the terms "accomplice" and "partnership" does not imply a prison partnership between Nortel and any other celebration.


    Nortel adds UC Capabilities to enterprise Communications supervisor | killexams.com existent Questions and Pass4sure dumps

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    BCM50/450 Rls. 5.0 Installation and(R) Initial Configuration

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    Atomic-level insight into super-efficient electrocatalytic oxygen evolution on iron and vanadium co-doped nickel (oxy)hydroxide | killexams.com existent questions and Pass4sure dumps

    Fabrication and characterization of Ni3Fe1−xVx

    A chain of Ni3Fe1−xVx (oxy)hydroxide catalysts (0 ≤ x ≤ 1), namely Ni3Fe, Ni3V, Ni3Fe0.67V0.33, Ni3Fe0.5V0.5, Ni3Fe0.33V0.67, and simple Ni (oxy)hydroxides were directly grown on hydrophilic CFPs by hydrothermal synthesis (Fig. 1 and Supplementary Fig. 1). The atomic ratios of different metals in the as-prepared catalysts were determined by analyses of inductively coupled plasma optical emission spectroscopy (ICP-OES, Supplementary Table 1).

    Fig. 1

    Fabrication of Ni3Fe1‒xVx/CFP O2-evolving electrodes. Schematic illustration of the fabrication procedure by directly growing Ni3Fe1‒xVx NSs on a pretreated CFP substrate

    The powder X-ray diffraction (PXRD) patterns (Supplementary Fig. 2) betoken that Ni3Fe1−xVx are isostructural to α-Ni(OH)2 (JCPDS Card No. 38-0715). The reflections at 2θ = 11.4° and 22.7°, corresponding to the (003) and (006) lattice planes of Ni3Fe1−xVx, slightly shift to larger 2θ values by 0.2° and 0.6°, respectively, relative to those of α-Ni(OH)2. The d-spacing values obtained from the (003) and (006) reflections are about 7.65 and 3.81 Å, respectively, with a miniature contraction compared to those for simple α-Ni(OH)2 (d(003) = 7.79 Å and d(006) = 3.91 Å), which is most possibly caused by the substitution of Fe and V atoms for Ni in the lattice sites of the Ni(OH)2 matrix32,39,40. Because no extra diffraction peaks are observed in the PXRD pattern, it could breathe deduced that no separated crystalline phases, such as unary Ni-, Fe-, or V-based oxides/(oxy)hydroxides, are formed during the doping process12,28,41.

    Scanning electron microscopic (SEM) images of Ni3Fe0.5V0.5/CFP (Fig. 2a) clearly prove that the entire surface of each carbon fiber is uniformly coated with the densely interlaced NSs, forming a sharp contrast to the smooth surface of pristine carbon fibers (Supplementary Fig. 3). A proximate inspection (Fig. 2b) reveals that the interlaced NSs profile a porous network structure. Such an open nanoarchitecture built by Ni3Fe0.5V0.5 ultrathin NSs would afford a mass of electrochemically lively sites, an facile penetration of electrolyte, and a sterling mechanical strength, so as to improve the OER activity and stability of the electrodes4. The quantitative SEM energy dispersive X-ray spectrum (SEM-EDX) of Ni3Fe0.5V0.5/CFP discloses the presence of Ni, Fe, V, and O elements with a Ni/Fe/V atomic ratio of 74.12:12.83:13.05, which is proximate to the stoichiometric metal ratio of Ni/Fe/V = 3:0.5:0.5. Moreover, the corresponding elemental mappings (Supplementary Fig. 4) illustrate that the Ni, Fe, V, and O elements distribute homogenously on the surface of carbon fibers.

    Fig. 2

    Microscopy measurements of Ni3Fe0.5V0.5 NSs. a, b Top-view SEM images of the carbon fiber coated with Ni3Fe0.5V0.5 NSs with low (a) and lofty (b) magnification. Scale bars, 1 μm in a and 100 nm in b. The inset in a shows the hierarchically structured 3D integrated electrode. Scale bar in the inset in a, 5 μm. c, d TEM images of Ni3Fe0.5V0.5 NSs scratched off from the as-prepared CFP electrode. Scale bars, 100 nm in c and 40 nm in d.e Atomic-resolution BF-TEM image of Ni3Fe0.5V0.5 NSs. Scale bar, 1 nm. f Aberration-corrected HAADF-STEM image of Ni3Fe0.5V0.5 NSs, the corresponding EDX elemental mappings of Ni, Fe, V, O and the mixed elemental mapping of Ni, Fe, V, and O. Scale bar, 2 nm

    The bright-field TEM (BF-TEM) image (Fig. 2c) of Ni3Fe0.5V0.5 NSs illustrates a rippled sheet structure with a dimension around 500 nm, and the lateral TEM image (Fig. 2d) shows the ultrathin Ni3Fe0.5V0.5 NSs with the thickness of 2.7–4.2 nm. Furthermore, the atomic-resolution BF-TEM image (Fig. 2e) displays transparent lattice fringes with an interplanar spacing of 2.67 Å, indexed to the (101) plane of Ni3Fe0.5V0.5 NSs. The interplanar spacing of lattice fringes is slightly smaller than that of α-Ni(OH)2 (2.68 Å) due to the doping of Fe and V for Ni in Ni(OH)2 lattices. separate atoms, clusters, and miniature particles of Fe and V species are not observed in aberration-corrected high-angle annular dark-field scanning TEM (HAADF-STEM) images of Ni3Fe0.5V0.5 NSs (Supplementary Fig. 5). Meanwhile, both the EDX elemental mappings and linear scanning analysis of the HAADF-STEM image of Ni3Fe0.5V0.5 NSs with sub-nanometer resolution (Fig. 2f and Supplementary Fig. 6) provide direct-viewing evidence for the uniform distribution of Ni, Fe, V, and O elements in the as-prepared NSs.

    In order to clarify the occupation sites of Fe and V dopants in Ni(OH)2 lattices, they array in Fig. 3 the FT curves of the Fe and V K-edge EXAFS k2χ(k) functions for Ni3Fe, Ni3V, and Ni3Fe0.5V0.5. As references, their Ni K-edge FT curves are moreover plotted (Fig. 3a). The FT curves of the Fe K-edge data of Ni3Fe and Ni3Fe0.5V0.5 exhibit two prominent coordination peaks at 1.5 and 2.7 Å that are identical to those of their Ni K-edge data (Fig. 3b), suggesting the substitutional doping of Fe in the Ni(OH)2 host. Similarly, the FT curves of Ni3V and Ni3Fe0.5V0.5 each array a prominent V–O peak at 1.4 Å and a V–M (M = Fe, Ni, or V) peak at about 2.8 Å (Fig. 3c), and the high-shell peak of Ni3Fe0.5V0.5 is weaker than that of Ni3V. The significant lessen in the intensity of the V–M coordination peak in the FT curve of Ni3Fe0.5V0.5 is most likely caused by the highly distorted local structure of V substituting for the site of Ni. To corroborate the substitution of V for Ni in Ni(OH)2 lattices, the WT analysis of the V K-edge data was performed. A maximum at the cross point of R = 2.8 Å and k = 7.8 Å−1 appears in the EXAFS WT map at the V K-edge for Ni3Fe0.5V0.5 (Supplementary Fig. 7), just fancy that for Ni3V. This implies the presence of V–Fe/Ni scatterings at a distance of around 2.8 Å surrounding V atoms and affords direct evidence for the substitution of V atoms for the Ni sites in Ni(OH)2 lattices. They moreover made the calculation of the EXAFS spectra by assuming V adsorption on the Ni–Fe LDH layer or occupying the interstitial position. It turns out that in both cases the calculated spectra are quite different from the experimental V K-edge EXAFS spectra of Ni3Fe0.5V0.5 (Supplementary Fig. 8). Furthermore, DFT calculations intimate that V atoms initially placed on the top site of surface Ni or O atoms are relaxed to the interstitial between two LDH layers after structure optimization. The LDH structure with interstitial doping is noticeably buckled, with formation energy of −3.73 eV per V atom, less stable with esteem to LDH with substitutional doping (−5.07 eV per V atom) (Supplementary Figs. 9, 10), supporting that V atoms occupy Ni positions in Ni(OH)2 lattices rather than the interstitial or top positions of LDH layers. On the other side, from Supplementary Fig. 11, the nearest-neighbor FT peak position of V is shifted to the lower-R side and the second coordination peak to higher-R side with apparently reduced intensity as compared to that of Fe. This implies the remarkable different local environment of the substitutional V from that of Fe in Ni3Fe0.5V0.5. The quantitative parameters extracted from EXAFS curve-fitting (Supplementary Figs. 12‒14 and Supplementary Tables 2‒4) further prove that the bond length of V–O (1.72 Å) is significantly contracted with esteem to those of Fe–O (2.00 Å) and Ni–O (2.03 Å).

    Fig. 3

    XAS spectra of the as-prepared Ni-based (oxy)hydroxide catalysts. FT curves of a Ni K-edge, b Fe K-edge, and c V K-edge EXAFS k2χ(k) functions

    Understanding the electronic interaction in Ni3Fe1−xVx

    The electronic states of Fe and V in catalysts were investigated by ex-situ difficult X-ray absorption near-edge spectroscopy (XANES). Generally, in XANES spectra the intensity of the pre-edge peak depends predominantly on central site symmetry, while the absorption edge position is correlated to the oxidation condition of central sites42. The absorption edges of Ni3Fe, Ni3V, and Ni3Fe0.5V0.5 in the XANES curves of Ni K-edge (Supplementary Fig. 15a) are totality alike to that of the original Ni(OH)2, indicative of nearly identical middling oxidation states of Ni in the catalysts. Similarly, the XANES curves of Fe K-edge in Supplementary Fig. 15b prove that the adsorption edges of Fe for Ni3Fe, Ni3Fe0.5V0.5, and Fe2O3 reference are almost overlapped, manifesting that the middling valence states of Fe are proximate to +3 in the as-prepared catalysts. Importantly, the V K-edge XANES spectra of Ni3V and Ni3Fe0.5V0.5 exhibit violent pre-edge peaks (Supplementary Fig. 15c), indicating the distorted coordination environment around V atoms in these materials42. More interestingly, Ni3Fe0.5V0.5 shows a higher pre-edge peak than that of Ni3V in the V K-edge XANES, implying a higher degree of octahedral geometry distortion at the V sites in Ni3Fe0.5V0.5 compared to those in Ni3V. Additionally, the K-edge absorption positions of Ni3V and Ni3Fe0.5V0.5 are more proximate to those of VO2 and V2O5 than to that of V2O3 (inset of Supplementary Fig. 15c), suggesting that the majority of V ions are in the formal valences of +4 and +5 in both catalysts.

    The as-prepared Ni3Fe1−xVx films were further studied by XPS and ex-situ soft XAS to gain an insight into the electronic interaction between Fe/V dopants and Ni atoms at the surface of catalysts. For Ni3Fe0.5V0.5 NSs, the Ni 2p spectrum (Fig. 4a) exhibits two fitting peaks at 872.3 and 854.4 eV along with two shakeup satellites at 878.4 and 860.1 eV, which are characteristic spin-orbit peaks of Ni2+ (refs. 13,28,43). In the Fe 2p region (Fig. 4b), Fe 2p1/2 and Fe 2p3/2 peaks arise at 724.8 and 711.5 eV, indicative of Fe in the +3 oxidation condition (refs. 16,29). The V 2p3/2 peak (Fig. 4c) can breathe deconvoluted into three peaks located at 516.2 eV (V5+), 515.1 eV (V4+), and 514.4 eV (V3+) (refs. 26,28,29), demonstrating that the V atoms are predominantly in lofty oxidation states (+4 and +5) in Ni3Fe0.5V0.5, together with a minority of V3+, which is consistent with the results obtained from V K-edge XANES spectra.

    Fig. 4

    High-resolution XPS and XANES spectra of the as-prepared Ni-based (oxy)hydroxide catalysts. XP spectra of a Ni 2p for Ni3Fe0.5V0.5, Ni3Fe, Ni3V, and simple Ni (oxy)hydroxides, b Fe 2p for Ni3Fe and Ni3Fe0.5V0.5, and c V 2p for Ni3V and Ni3Fe0.5V0.5 (the dashed lines shown in a–c betoken the shifts of BEs  of 3d metal ions caused by the hybridization of Fe or/and V dopants). d–f Ni, Fe, and V L-edge XANES spectra. g Schematic representations of the electronic coupling among Ni, Fe, and V in Ni3Fe, Ni3V, and Ni3Fe0.5V0.5

    It is worthy of note that the Ni 2p BEs for the Fe or/and V doped binary and ternary materials are shifted apparently to higher BEs compared to those of simple Ni (oxy)hydroxide, with the shift extent in an increasing order of Ni3Fe < Ni3V < Ni3Fe0.5V0.5 (Fig. 4a, Supplementary Fig. 16a, and Supplementary Table 5). In contrast, the V 2p peaks for Ni3V are shifted to lower BEs relative to the corresponding peaks for VO2 (ref. 44), and Ni3Fe0.5V0.5 displays V 2p3/2 peaks at BEs ~0.2 eV lower than those of Ni3V (Fig. 4c and Supplementary Fig. 16c). Of particular interest is that the BEs of Fe 2p1/2 and 2p3/2 for Ni3Fe are lower than those for Fe2O3 (ref. 45), but when half amount of Fe in Ni3Fe is replaced by V, Ni3Fe0.5V0.5 exhibits Fe 2p peaks at BEs not only considerably higher than those of Ni3Fe but moreover higher than Fe2O3 (Fig. 4b and Supplementary Fig. 16b), implying that the Fe dopant acts as an electron accepting site in Ni3Fe but an electron donating site in an integrated upshot when V is co-doped with Fe into Ni(OH)2 lattices. These observations intimate the partial electron transfer from Ni to Fe or V in the bimetal (oxy)hydroxides through oxygen bridges (O2−) between metal ions, and from Ni and Fe to V in Ni3Fe0.5V0.5, which is in sterling agreement with the calculated Mulliken charges for V, Fe, and Ni ions in Ni3Fe1−xVx (Supplementary Table 6).

    These speculations are further supported by the Ni, Fe, and V L-edge XANES spectra shown in Fig. 4d‒f. Figure 4d illustrates that doping Fe or V could intensify the Ni L3-edge peak (852.5 eV), indicative of partial electron transfer from Ni to the substitutional Fe or V. The intensity of the Fe L3-edge peak at 709.8 eV for Ni3Fe is moreover enhanced when V is doped into Ni3Fe (Fig. 4e). On the contrary, the V L3-edge peak (518.3 eV) of Ni3Fe0.5V0.5 is considerably weakened and shows a red-shift, as compared with that of Ni3V (Fig. 4f). The comparative analyses of XPS and XANES spectra intimate that co-doping of Fe together with V into Ni(OH)2 lattices results in more electron transfer to the V in Ni3Fe0.5V0.5 compared to that in Ni3V (Fig. 4c, f and Supplementary Fig. 16c). The tenacious interaction among these 3d metal ions results in synergistic modulation of the electronic structure of the metal centers of Fe/V co-doped Ni(OH)2 (refs. 12,22,36,43), and the concerted upshot of Ni, Fe, and V metals with different energy levels of d-band centers could manufacture crucial contribution to the evident enhancement of OER activity of hybridized materials. Moreover, they calculated the branching ratio, L3/(L2 + L3), at the Fe L-edges of Ni3Fe and Ni3Fe0.5V0.5, which is approximately 0.74, implying the high-spin of Fe3+ (ref. 46). And they moreover calculated the Fe L2,3-edge XAS for the high-spin and low-spin models of Fe3+ (Supplementary Note 1 and Supplementary Methods). Obviously, the calculated high-spin L2,3-edge XAS could well produce the experimental data (Supplementary Fig. 17), affording more evidence for the high-spin configuration of Fe3+ substituting the Ni sites. Thus, the valence electronic configurations of Ni2+, Fe3+, V4+, and V5+ are 3d8 (t2g6eg2), 3d5 (t2g3eg2), 3d1 (t2g1eg0), and 3d0 (t2g0eg0), respectively, which are adopted in the following analysis of valence electron structures of metal ions in Ni3Fe, Ni3V, and Ni3Fe0.5V0.5.

    The synergistically electronic interplay of Ni, Fe, and V cations in Ni3Fe0.5V0.5 is well explained in light of the analysis of valence electron structures of metal ions. In term of the result obtained from DFT calculations that the (Ni3Fe0.5V0.5)-OOH models with some aggregated Fe and V atoms accommodate lower formation energy and higher OER activity than the models with isolated Fe and V atoms (vide infra), a Ni–O–Fe–O–V–O–Ni unit (Fig. 4g) is used to analyze the electronic interaction of Ni, Fe, and V cations in Ni3Fe0.5V0.5. For Ni3Fe, the three unpaired electrons in the π-symmetry (t2g) d-orbitals of Fe3+ interplay with the bridging O2− via π-donation, while the paramount interaction between the fully occupied π-symmetry (t2g) d-orbitals of Ni2+ and the bridging O2− is electron–electron repulsion, leading to partial electron transfer from Ni2+ to Fe3+ (refs. 12,40). The partial electron transfer from π-symmetry lone pairs of the bridging O2− to V4+ and V5+ in Ni3V should breathe stronger than that from the bridging O2− to Fe3+ in Ni3Fe, as V4+ and V5+ accommodate rather low t2g occupancy while Fe3+ has a half t2g occupancy. As for the Fe/V co-doped Ni(OH)2 with some of the V and Fe atoms aggregated in the host lattices, when Fe3+ accepts partial electrons from Ni2+ through the bridging O2− via π-donation as exampled by the NiFe (oxy)hydroxide reference, the electron-riched t2gd-orbitals of Fe3+ could relay electrons to the strongly electron-deficient t2gd-orbitals of V4+ and V5+ through the bridging O2− ions between them, which leads to better delocalization of the π-symmetry electrons among Ni, Fe, and V in the host matrix. This argument is in sterling agreement with the XPS and soft XANES results. In Ni3Fe1−xVx, the Fe3+ and Ni2+ with half-full eg orbitals would accommodate very debilitated bonding with adsorbed oxygen species, whereas the V4+ and V5+ with eg0 orbitals would profile too tenacious bonding with adsorbed oxygen species. To collect lofty OER activity, the bonding power between transition metal and adsorbed oxygen species should breathe optimized to fulfill the Sabatier principle47. With enlarge of the electron density on V by partial electron transfer from Fe and Ni to V through the bridging O2− ions, the lofty valence states of V could breathe stabilized under OER conditions, and more importantly, the tenacious bond power between V and adsorbed oxygen species could breathe tuned to a temper bond strength, which would profit for releasing O2 from the V site in OER.

    Evaluating the electrochemical OER performance of Ni3Fe1−xVx

    The electrocatalytic OER performance of Ni3Fe1−xVx/CFP were studied in O2-saturated 1 M KOH. The linear sweep voltammograms (LSVs, Fig. 5a) of totality as-prepared Ni-based (oxy)hydroxide catalysts prove the Ni2+/Ni3+ oxidation in the potential sweep of 1.33–1.42 V (all potentials are versus reversible hydrogen electrode (RHE))5,7,43.

    Fig. 5

    Electrochemical tests for OER and Nyquist plots of the Ni-based (oxy)hydroxide catalysts. a LSV curves of Ni3Fe1−xVx and simple Ni (oxy)hydroxide catalysts on CFP, as well as bare CFP in O2-saturated 1 M KOH at a scan rate of 5 mV s−1. b Tafel plots derived from the polarization curves in a. c Chronopotentiometric curves obtained with Ni3Fe0.5V0.5 at constant current densities of 10 and 100 mA cm−2. d Nyquist plots of Ni3Fe0.5V0.5, Ni3Fe, Ni3V, and Ni (oxy)hydroxides and the bare CFP at 300 mV overpotential in 1 M KOH

    Figure 5a illustrates that the electrocatalytic activity of Ni3Fe1−xVx depends largely on the co-doping even of Fe and V atoms. Among the as-prepared Fe- or/and V-doped Ni-based binary and ternary catalysts, Ni3Fe0.5V0.5 exhibits the best OER performance, with low overpotentials of 264 and 291 mV to achieve 100 and 500 mA cm−2 current density, respectively (Supplementary Fig. 18). The LSV of Ni3Fe0.5V0.5, scanning from positive to negative direction to exclude the influence of the Ni2+/Ni3+ oxidation event on the catalytic current, shows that only 200 mV overpotential is required to attain 10 mA cm−2 current density. The OER performance of Ni3Fe0.5V0.5 is on a par with or even surpasses that of the first-class earth-abundant catalysts reported to date (Supplementary Table 7).

    Moreover, the turnover frequency (TOF, based on total amount of metals) of Ni3Fe0.5V0.5 (0.574 s−1) at η = 300 mV in 1 M KOH is significantly larger than those of Ni3Fe (0.018 s−1), Ni3V (0.097 s−1), Ni3Fe0.67V0.33 (0.116 s−1), and Ni3Fe0.33V0.67 (0.195 s−1). Figure 5b manifests that the Tafel slope of Ni3Fe0.5V0.5 (39 mV dec−1) is considerably smaller than those of Ni3Fe0.67V0.33 (59 mV dec−1), Ni3Fe0.33V0.67 (54 mV dec−1), Ni3Fe (67 mV dec−1), and Ni3V (67 mV dec−1). The apparently larger TOF value and smaller Tafel slope of Ni3Fe0.5V0.5 as compared to those of Ni3Fe and Ni3V betoken that the synergetic upshot of co-doped Fe and V plays an notable role in facilitating the kinetics of OER and enhancing the intrinsic activity.

    The stability of Ni3Fe0.5V0.5 was assessed by repeated cyclic voltammetry scanning, multi-current step test, and long-term chronopotentiometric experiments. After being subjected to 4000 CV cycles, the OER polarization curve of Ni3Fe0.5V0.5 almost overlaps with the initial one (Supplementary Fig. 20a), indicating no noticeable loss in catalytic current, and thus, the sterling accelerated stability of the electrode. Supplementary Fig. 20b shows the E–t plot of two cycles of multi-current step curves for Ni3Fe0.5V0.5 with current density being enhanced from 50 to 500 mA cm−2 by five steps. In each step, once a certain current density is set, the potential promptly levels off and maintains constant for 500 s; the multi-current step curve is well repeated in the subsequent cycle. This observation signifies lickety-split mass transportation and sterling electronic conductivity of the 3D Ni3Fe0.5V0.5/CFP matrix13. Additionally, the Ni3Fe0.5V0.5/CFP electrode displays sterling stability at fixed current densities of 10 and 100 mA cm−2, respectively, over 60 h of electrolysis (Fig. 5c), indicating excellent stability of the electrode under testing conditions. The Faradaic efficiency of Ni3Fe0.5V0.5 evaluated from a chronopotentiometric experiment at a constant current density of 10 mA cm−2 for 2 h is proximate to 100% (Supplementary Fig. 21).

    To accommodate a common understanding on the superior activity of Ni3Fe0.5V0.5, they estimated the roughness factors (RF) and measured the electrochemical impedance spectroscopy (EIS) of totality as-prepared Ni-based electrodes. Based on the estimated RF values (Supplementary Fig. 22 and Supplementary Note 2), the OER polarization curves of Ni3Fe1−xVx were ploted with J normalized by RF values (Supplementary Fig. 23) to appraise the improvement of intrinsic OER activity for the Ni-based (oxy)hydroxides with different Fe and V doping levels3. The specific current density (Js = 61.6 mA cm−2) of Ni3Fe0.5V0.5 at 300 mV overpotential is about 3, 16, and 71 times higher than those of Ni3V, Ni3Fe, and simple Ni (oxy)hydroxides, respectively, which reveals that the co-doping of Fe and V into Ni(OH)2 lattices is much more efficacious than separately doping Fe or V for improving the specific activity of Ni-based catalysts, and the improved specific activity contributed largely to the lofty OER activity of Ni3Fe0.5V0.5. The Nyquist plots (Fig. 5d) are fitted to a simplified Randles equivalent circuit model (Supplementary Note 3). The very miniature semicircles in the lofty frequency zone are attributed to the internal charge-transfer resistances (Rct(int)) of electrodes, and the second semicircles limn the charge-transfer resistances (Rct(s–l)) at the electrode/electrolyte interface. Both Rct(int) and Rct(s–l) values apparently decreased as Fe and V were co-doped into Ni(OH)2 lattices. The total charge-transfer resistances (Rct) measured at 300 mV overpotential are 4.2, 7.2, 10.0, and 17.2 Ω for the CFP-supported Ni3Fe0.5V0.5, Ni3V, Ni3Fe, and simple Ni (oxy)hydroxides, respectively (Supplementary Table 9). The excellent charge-transfer capability of Ni3Fe0.5V0.5 makes a crucial contribution to the superior intrinsic OER activity of the electrode48.

    In-situ EC-Raman/XAS studies and speculative calculations

    To accommodate an in-depth insight into the inception of lofty activity of the Fe/V co-doped Ni(OH)2, the changes in electronic structures and local atomic environments of Ni3Fe0.5V0.5 under OER conditions were studied by in-situ electrochemical Raman (EC-Raman) spectroscopy and in-situ XAS. The measurements of in-situ EC-Raman spectra were carried out at the potential sweep of 1.0–1.8 V in a spectroelectrochemical (PEC) cell filled with 1 M KOH electrolyte (Fig. 6a). When the applied potential was higher than 1.4 V, a pair of well-defined Raman peaks at around 470 and 550 cm−1 appeared, which were correlated respectively with the eg bending and the A1g stretching vibration of Ni–O in the NiOOH-type phase49,50. On the basis of EC-Raman spectra, the host facet of NiIII–OOH, formed during the OER process, could provide an electrically conductive, chemically stable, and electrolyte-permeable framework for the Fe and V dopants48,51, which would profit the electrochemical OER.

    Fig. 6

    In-situ EC-Raman and difficult XAS spectra. a In-situ EC-Raman spectra of Ni3Fe0.5V0.5 at the potentials of 1.0–1.8 V in 1 M KOH. b, d, f In-situ Ni, Fe, and V K-edge XANES spectra at the potentials of 1.15–1.75 V. c, e, g FT curves of Ni, Fe, and V K-edge EXAFS k2χ(k) functions obtained from the XANES spectra in b, d, f, respectively. The orange and pink circles limn the fitting values

    Furthermore, the alteration in the local coordination environment of Ni–O/Fe–O/V–O units and the middling oxidation states of Ni, Fe, and V centers in Ni3Fe0.5V0.5 were investigated by in-situ difficult XAS (Supplementary Fig. 24). The in-situ Ni K-edge XANES spectra (Fig. 6b) prove that the Ni absorption-edge and the white-line are gradually shifted to the higher-energy side as the applied potential is increased from 1.15 to 1.75 V. Accordingly, the Ni–O distance is shortened from 2.04 Å at 1.15 V to 1.90 Å at 1.75 V (Fig. 6c and Supplementary Table 8). The former is proximate to the Ni–O bond length (2.05 Å) in Ni(OH)2, and the latter is almost identical with the Ni–O bond length (1.88 Å) in NiOOH, which contains a amalgam of Ni3+ and Ni4+ sites10. This is in line with the results of in-situ EC-Raman spectroscopy. A similar shift of the Fe white-line peak toward the higher-energy side is moreover observed with increasing applied potential (Fig. 6d), and the Fe–O distance is shortened slightly from 2.00 Å at 1.15 V to 1.97 Å at 1.75 V (Fig. 6e and Supplementary Table 8), signifying that the oxidation condition of Fe is increased from +3 to nearly +4 during the OER electrolysis process of Ni3Fe0.5V0.5. These FT-EXAFS fitting results of Ni and Fe K-edges of Ni3Fe0.5V0.5 in both relaxation and activated states are consistent with the previous reports10,14. More interestingly, with increasing the applied potential from 1.15 to 1.75 V, the pre-edge peak is slightly decreased in intensity in the in-situ V K-edge XANES spectrum (inset of Fig. 6f), however, it shows identical spectral features to those measured before OER. Similarly, except for the lessen in the intensity of the characteristic peaks, no other obvious change is visible at the ex-situ V L-edge spectra (Supplementary Fig. 25) after OER measurement at 1.75 V. This evidence suggests partial electron transfer to the V 3d orbitals, as their peak intensity is proportional to the unoccupied density of 3d states. Meanwhile, the V–O1 distance is moreover shrunk from 1.70 Å at 1.15 V to 1.65 Å at 1.75 V (Fig. 6g and Supplementary Table 8), which is proximate to that of the shortest V–O bond length reported for V5+ oxides (1.59 Å) while much shorter than that reported for V4+ oxides (1.76 Å)42. The V atoms with such a short V–O bond may accommodate optimal binding capability with oxygen intermediates relative to Ni and Fe atoms, and exhibit enhanced OER activity, as will breathe illustrated by following speculative calculations. These in-situ XAS analyses manifest for the first time the contraction of M–M′ and M(M′)–O bond lengths and the short V–O bond distance in the activated V-containing (oxy)hydroxide OER catalysts.

    DFT plus Hubbard U (DFT + U) calculations were conducted to accommodate a speculative understanding on the evident enhancement of OER activity of the Fe/V co-doped Ni(OH)2 from atomic level. It is known that Ni(OH)2 experiences facet transformations during charging and discharging, and its oxyhydroxides are proposed to breathe the lively facet for OER14,52,53. Thus, they deem β-NiOOH co-doped by V and Fe atoms with the experimentally optimized doping concentration of Ni:Fe:V = 6:1:1, as well as the systems doped by only V or Fe atom with Ni:V (Fe) = 3:1 (Fig. 7a and Supplementary Fig. 26). The model surfaces are covered by either water molecules or oxygen species that are possibly present in the reaction media. These models with different covered species give very similar results on the catalytic properties (Fig. 7c and Supplementary Table 6).

    Fig. 7

    DFT speculative models. a Side views of the Fe/V co-doped Ni (oxy)hydroxide model for DFT calculations, whose (101) surface is exposed for OER catalysis. b Structures and BEs of an OH*, O*, and OOH* intermediates adsorbed on the V site of the model in a with the lowest OER overpotential of 0.25 V. The surface metal atoms are covered by O species. c Volcano plot of OER overpotential versus BE contrast between OH* and O* species for various sites of Ni3Fe1−xVx (oxy)hydroxide models. For each ilk of reaction site, various structural models are considered, whose circumstantial information is given in Supplementary Fig. 28 and Supplementary Table 6. The dashed line is a guide for eyes. d Left panel: DOS of the model in a and the projected DOS on s, p, and d orbitals. perquisite panel: projected DOS on the 3d orbitals of Ni, Fe, and V atoms in the model. The dashed lines limn the d-band hub for each element. The Fermi even is shifted to zero. e Calculated free-energy diagram of OER on the most lively site of Ni3Fe0.5V0.5 (oxy)hydroxide in pH 14 solutions at different potentials (T = 298 K). The two-way arrow indicates the overpotential of the rate-limiting step

    In the optimized models, the bond lengths between metals and oxygen intermediates are 1.60–1.84, 1.63–1.95, and 1.77–2.05 Å for V, Fe, and Ni, respectively, which are in sterling agreement with the trend of experimental XAS results. The distinct bond length between O atom and V, Fe, or Ni ingredient is a reflection of their different bond order and bond strength, which is fundamentally governed by the electronic troupe structure of the material. As revealed by the density of states (DOS) in Fig. 7d, the V, Fe, and Ni atoms in the co-doped Ni(OH)2 accommodate the d-band hub of 0.09, −2.55, and −2.78 eV, respectively. On the basis of the d-band theory54, the V atoms with higher d-band hub possess less occupancy of the antibonding states with adsorbed oxygen intermediates, and thus exhibit optimal binding with esteem to Ni and Fe atoms (Fig. 7c).

    Mulliken suffuse analysis55 shows partial charges of ~1.6, 1.0, and 0.8e on the V, Fe, and Ni sites, respectively, signifying the stronger metallicity of V atoms and higher chemical activity. Although DFT calculations cannot identify the exact valence for each metal in multi-metal materials, the trend of the partial charges on the V, Fe, and Ni sites obtained from Mulliken suffuse analysis is consistent with that of the valences of V4+/5+, Fe3+, and Ni2+ estimated on the basis of XANES and XPS. Moreover, the Ni (oxy)hydroxide systems without V doping are half-metal (Supplementary Fig. 27), while the V doping induces finite DOS for the spin-down states near the Fermi even (Fig. 7d), which may succor improve the electrical conductivity of the material.

    In the previously reported mechanism for 3d metal-based (oxy)hydroxide catalysts in alkaline media, the OER undergoes through following four elementary steps56,57:

    $$^\ast + {\mathrm{OH}}^ - \to {\mathrm{OH}} ^\ast {\mathrm{ + }}e^ -$$

    (1)

    $${\mathrm{OH}} ^\ast {\mathrm{ + OH}}^ - \to {\mathrm{O}} ^\ast + {\mathrm{H}}_2{\mathrm{O}}\left({\mathrm{l}} \right) + e^ -$$

    (2)

    $${\mathrm{O}} ^\ast + {\mathrm{OH}}^ - \to {\mathrm{OOH}} ^\ast + e^ -$$

    (3)

    $${\mathrm{OOH}} ^\ast + {\mathrm{OH}}^ - \to ^\ast + {\mathrm{O}}_2\left( {\mathrm{g}} \right) + {\mathrm{H}}_2{\mathrm{O}}\left({\mathrm{l}} \right) + e^ -$$

    (4)

    where * represents an lively site on the leavening surface; OH*, O*, and OOH* are the oxygen intermediates. To evaluate the OER activity of the Fe and/or V doped or simple Ni (oxy)hydroxide systems, they computed the BEs of oxygen intermediates on various metal sites. The Gibbs free energy for each reaction step and speculative OER overpotentials were calculated with the criterion hydrogen electrode (SHE) method58.

    As displayed by Fig. 7c, the OER overpotentials of doped Ni (oxy)hydroxides follow a volcano-shape relation with the breathe contrast between OH* and O* (or OOH*) species59. In particular, oxygen binding on the Fe and Ni sites is relatively weak, i.e. EOH* > 1.15 eV and EO*–EOH* > 2.24 eV. As a consequence, formation of OH* and O* species encounters big potential barriers (Supplementary Fig. 29a, b) and will restrict the reaction rate of OER process. big overpotentials of 0.72–0.79 and 0.84–1.08 V are obtained for the Fe and Ni sites, respectively, indicating their low activity for OER. By contrast, the V sites provide much stronger but temper oxygen binding power (EOH* = 0.47–0.79 eV and EO*–EOH* = 1.61–2.23 eV) and give near-optimal BEs of OER intermediates. Reactions to the formation of OH* and O* species are readily accessible, while formation of OOH* experiences the largest potential barrier and limits the OER rate, giving overpotentials of 0.25–0.63 V, which are much lower than those for Ni and Fe sites. Therefore, the highest activity is predicted on the V site of the co-doped Ni (oxy)hydroxide with some of the V and Fe atoms aggregated (Fig. 7b). Such V sites provide tenacious OOH* binding relative to O* species, and the overpotential is even lower than that of the benchmark leavening RuO2, i.e., 0.40 V for the (110) surface according to their calculations. The inception of overpotentials is clearly revealed by the free-energy diagrams as shown in Fig. 7e and Supplementary Fig. 29. The largest potential step at the equilibrium potential (U = 0.402 V) indicates the rate-limiting step (RLS) and corresponding overpotential, by overcoming which totality the OER steps become downhill and thus can occur spontaneously from the thermodynamic point of view (Supplementary Note 4). In general, the speculative OER overpotentials follow the very trend as the experimental values: Fe/V co-doped < V-doped < Fe-doped < undoped Ni (oxy)hydroxide (Supplementary Fig. 28 and Supplementary Table 6). DFT calculations prove that the OER activity of V sites doped in Ni3Fe0.5V0.5 was greatly enhanced by the surrounding Ni/Fe next-nearest neighbors, and more importantly, the (Ni3Fe0.5V0.5)-OOH models with some of Fe and V atoms aggregated in NiOOH lattices accommodate lower formation energy and higher OER activity than the models with isolated Fe and V atoms. This inference is conform with the statement made by Bell and Calle-Vallejo et al. that for Fe-doped Ni (oxy)hydroxides the surrounding Ni neighbors enlarge the activity of Fe sites10,60,61.


    Software Design Document, Testing, Deployment and Configuration Management of the UUIS--a Team 2 COMP5541-W10 Project Approach | killexams.com existent questions and Pass4sure dumps

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    About using Nix in my progress workflow | killexams.com existent questions and Pass4sure dumps

    Two years ago, whenever I needed to employ some language or implement which wasn’t available on my machine, I would accommodate used the system’s package manager to install it. It worked on my computer, but when I needed to reproduce the setup elsewhere it was another story. I was silent a student then.

    I bethink a group project in which they were using Node.js. I had a recent version installed on my Mac via Homebrew, while at the university and on other student’s computer based on Ubuntu Linux, it was installed from the default repos. Then, my code using default parameters in functions would dash on my machine but not on other’s, since their Node.js version was greatly outdated.

    Using this approach can quickly become a nightmare, especially when you try to write a documentation on how to set up the progress environment. You cessation up writing things like: “If you are on macOS tickle execute this, on Debian execute that, and Fedora dash this other command.” You can verify it works now, but there is no guarantee it will silent work in a few months.

    asdf

    At the cessation of my studies, while starting my internship, I started to execute a lot more software progress at home. Mainly because I didn’t accommodate to worry anymore about not doing my homework. This is back then I discovered Elixir and started to build up my workflow, seeking for quality, reproducibility and joy of use. With my Node.js record in mind, I discovered language version managers. I went for asdf as it would handle for me quite a bunch of languages, including Erlang, Elixir, Node.js and Ruby.

    If you are not close with it, asdf can install exactly the version you want for each language it handles through a plugin system. You can even accommodate multiple versions installed on the very machine and set the wanted one for every project using a .tool-versions file which looks fancy this:

    erlang 21.0elixir 1.7.3-otp-21

    It is simple to use, and you can set up easily your build environment on different machines, running asdf install in a project directory.

    Yet, if the setup process is simplified, there are silent issues:

  • after installing asdf, you necessity to install totality the needed plugins. It is only a matter of asdf plugin-install <plugin-name> commands, but it is not automated;
  • some languages require dependencies to build. Erlang, for instance, needs some packages to breathe installed before asdf install erlang <version> works. You necessity a compiler, ncurses, OpenSSL and quite a few more. Setup instructions depends on the system you use;
  • If your project depends on other tools like, say, fwup for Nerves projects, you silent accommodate to provide manual setup instructions.
  • This is where Nix enters the game.

    Nix

    Nix defines itself as The Purely Functional Package Manager. Having scholarly the advantages of Functional Programming while using Elixir and looking at Haskell and other FP languages over the past year, its concept was very tempting to me.

    Being purely functional means given an input, you always collect the very output. That is, given a version of nixpkgs and a set of packages, you always collect the very environment. In fact, packages are named derivations in the Nix jargon: they are functions that takes other derivations — their dependencies — as input and produce a derived result. They are built in isolation, so totality dependencies must breathe explicitely stated. This ensures reproducibility.

    Nix stores totality the built derivations in the Nix store, usually located at /nix/store. A very package can breathe present multiple times in the Nix store, at different versions or even at the very version but using different versions of its dependencies. Remember: a built derivation is the product of totality its dependencies; if you change something, it is a different product.

    To achieve a unique naming for each derivation, a hash is computed from the set of its dependencies. You then collect a path like:

    /nix/store/k13mm9jqxm2ndlwzsj7zicsq7lpmmjlg-elixir-1.7.3

    Unlike other package managers, Nix does not employ the conventional /{,usr,usr/local}/{bin,sbin,lib,share,etc} directories. Instead, it uses a lot of symbolic links to create profiles. A profile is a benign of derivation used to setup a user environment. In a profile, you collect a criterion Unix tree with symbolic links to executables and configuration files stored in other derivation outputs. For instance,~/.nix-profile/bin/elixir is a symbolic link to:

    /nix/store/k13mm9jqxm2ndlwzsj7zicsq7lpmmjlg-elixir-1.7.3/bin/elixir

    Actually, ~/.nix-profile is itself a link:

    ~/.nix-profile -> /nix/var/nix/profiles/per-user/***/profile

    Which itself points to profile-56-link wich finally points to somewhere in the Nix store:

    profile-56-link -> /nix/store/5yw8dnp9908ia6sdfvx01jzis4l2hni7-user-environment

    That is, as I accommodate said above, a profile is a derivation. It derives from a set of packages, that themselves derive from other packages. Depends on becomes in Nix derives from. This is conceptual but you collect the idea.

    Updating a symbolic link has the inspiring property of being an atomic operation. This enables atomic transactions: when performing an upgrade, a new user-environment derivation is built, with a different hash. Then, a new generation is created for the profile — understand: a new symbolic link profile-57-link pointing to the new derivation. Then, and only then, the profile link is updated to point to profile-57-link. You’ve just performed an atomic upgrade. If things went south, you’ve moreover got atomic rollbacks for free: just update again the profile link to point to profile-56-link and you are back in the past.

    Moreover, only what you asked for is made available in the environment. For instance, Elixir depends on Erlang. Erlang is then installed somewhere in the Nix store and the Elixir installation is aware of it so it can work correctly. But unless you explicitely asked to moreover install Erlang, only Elixir binaries will breathe linked in your user environment.

    Nix as a declarative configuration manager

    Package managers usually work in an imperative way. That is, you examine them to install this, to effect an upgrade or to uninstall that. One really dapper feature of Nix is Nix, the language. It is a purely functional domain-specific language that comes with Nix.

    The primary employ of Nix, the language, is to write derivations. Yet, different applications of Nix moreover leverage the language to manage packages and configuration declaratively. In NixOS — a special GNU/Linux distribution based on Nix — , totality the system configuration and globally installed packages are declared in /etc/nixos/configuration.nix. It can gawk like:

    { config, pkgs, ... }: {network.hostname = "nixos-test";time.timeZone = "Europe/Paris"; # Omitting a lot of options, this is just a sample. environment.systemPackages = with pkgs; [curlgitgnupghtop...];}

    To change the condition of the system, you just accommodate to edit the file, then examine NixOS to switch to the new environment:

    # nixos-rebuild switch

    It derives a new system environment, switches to it and reloads services as needed. With this benign of configuration, you can easily reproduce your system setup on different machines.

    Another sample is home-manager. It aims to provide the very benign of declarative configuration as NixOS but at the user level. I personally employ it to manage my dotfiles and my set of user-wide-available utilities accross different machines.

    Apart system and user environments, Nix can breathe used to setup a third benign of environment. Let’s talk about it.

    Nix as a reproducible environment builder

    It is neither practical nor wantable to update your system or user environment each time you necessity a particular dependency for a given project. First, the given dependency can breathe required only by a specific project: you execute not necessity to accommodate it available (system|user)-wide. Second, you want your environment to breathe shareable with other developers. Asking them to update their global environment with this or that requirement is not the best thing to do. This is where Nix shells enter.

    A Nix shell is a temporary environment where build inputs of a derivation are made available to the user. Let’s narrate it more simply with an example: you can create a shell.nix file at the root of your project containing something like:

    { pkgs ? import <nixpkgs> {} }: with pkgs; mkShell {buildInputs = [ ocaml git ];}

    Then, dash the nix-shell command. You are in a Nix shell, with OCaml and Git made available to you. The shell.nix can breathe committed, thus shared between developers.

    Using Nix

    To start working on a project using Nix, the first step is to install Nix itself. From the official documentation, totality you accommodate to execute is running:

    $ curl https://nixos.org/nix/install | sh

    There are in fact two kinds of installation for Nix:

  • the single-user installation, where /nix/store is owned by the user installing Nix. This is the simplest pass to install Nix if you are the only user on your machine and don’t want to employ Nix extensively outside of setting your progress environment. It is moreover the easiest to uninstall as you just accommodate to delete the /nix directory;
  • the multi-user installation, where /nix/store is owned by root and a nixbld group has write access to it. totality Nix operations are then performed by nix-daemon. Different users can employ Nix simultaneously and you gain a system environment fancy on NixOS. In the multi-user installation, builds are performed by special builder users in complete isolation. It is a limited bit more complicated to manage, but this is the recommended pass to install Nix if you pass to employ it a lot, even if you are the only user on your machine. It is supported on macOS and totality Linux running systemd with SELinux disabled.
  • As far as I know, the default installer currently choses automatically the ilk of installation. It could change in the near future to prompting the user for a choice. In the meantime, you can obligate how to install Nix by doing, for a single-user installation:

    $ sh <(curl https://nixos.org/nix/install) --no-daemon

    For a multi-user installation it is:

    $ sh <(curl https://nixos.org/nix/install) --daemon

    Nix being installed on you machine, you can create a shell.nix in your project:

    # This defines a duty taking `pkgs` as parameter, and uses# `nixpkgs` by default if no argument is passed to it.{ pkgs ? import <nixpkgs> {} }: # This avoids typing `pkgs.` before each package name.with pkgs; # Defines a shell.mkShell {# Sets the build inputs, i.e. what will breathe available in our# local environment.buildInputs = [ elixir git ];}

    Then, totality you accommodate to execute is running:

    $ nix-shell

    Nix will copy or build derivations, then dash a shell in which Elixir and Git are available. By default, the Nix shell is a bash. If you are fancy me and want to hold your sterling old-fashioned zsh for your day-to-day environment, there is an inspiring plugin for that.

    In a criterion Nix shell, your system-wide environment is silent available. While it is quite useful for day-to-day work, you can easily miss a dependency when first structure your environment. If you want to breathe certain not to miss any dependency and ensure reproducibility, you should dash a simple Nix shell, that is a Nix shell where only the inputs explicitely stated in the shell.nix are available:

    $ nix-shell --pure

    You slack totality your environment, totality your aliases, totality your usually available programs. You are in a standardised bash that will breathe the very on every machine where you dash a simple shell. It is not a cozy situation to work, but it is really cozy when your application builds in such a shell. It means any other developer or the future you will breathe able to setup the very environment and build the application as expected. But for your comfort, you can employ a criterion Nix shell most of the time.



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